TY - GEN AU - Camuffo, Dario TI - Microclimate for cultural heritage : measurement, risk assessment, conservation, restoration and maintenance of indoor and outdoor monuments SN - 9780444641069 U1 - 702.88 PY - 2019/// CY - Amsterdam PB - Elsevier KW - India--Khajurāho KW - Microclimatology KW - Art--Conservation and restoration KW - Monuments--Conservation and restoration KW - Architecture--Conservation and restoration KW - Architecture--Human factors KW - Great Britain N1 - Content Preface to the First Edition (1998) ix Preface to the Second Edition (2014) xi Foreword to the First Edition (1998) xiii Reviews to the First Edition ( 1998) xv Foreword to the Second Edition (2013) xix Preface to the Third Edition xxi Acknowledgements xxiii Credits xxv Author Biography xxix Part I THEORETICAL GROUNDS, KEY VARIABLES, MAIN DETERIORATION MECHANISMS 1. Microclimate and Atmospheric Variables 1.1 Microclimate 3 1.2 Air, Water Vapour, Perfect and Real Gases 7 1.3 The Internal Boundary Layer and the Viscous Layer 9 1.4 Coanda Effect 11 1.5 Atmospheric Variables and Parameters 12 References 13 2. Temperature: A Key Variable in Conservation and Thermal Comfort 2.1 Temperature: One Variable, Four Popular Definitions 15 2.2 Mechanisms of Temperature-Induced Deterioration 16 2.3 The Urban Heat Island 21 2.4 Temperature in a Building, a Room 22 2.5 Temperature in a Showcase 28 2.6 People's Thermal Comfort and Discomfort 30 2.7 Is It Possible to Combine People's Comfort, Conservation Needs, and Sustainability? 31 2.8 Planning Air Temperature Monitoring to Study Air-Surface Interactions and for Environmental Diagnostics 36 References 40 Further Reading 42 3. Theoretical Grounds for Humidity 3.1 Partial Pressure of Water Vapour 43 3.2 Derivation of the Latent Heat 44 3.3 Mixing Ratio of Water Vapour and Dry Air 46 3 .4 Specific Humidity 47 3.5 Absolute Humidity 48 3.6 Relative Humidity 48 3.7 Dew Point: The Temperature of Condensation 51 3.8 Frost Point: The Temperature of Freezing 52 3.9 Wet Bulb Temperature: The Temperature of Evaporation 53 3.10 The Psychrometric Chart 55 3.11 Humidity When It Rains or Snows 57 References 59 Further Reading 59 4. Consequences of the Maxwell-Boltzmann Distribution 4.1 The Maxwell-Boltzmann Equation and the Distribution of Molecules by Velocities 61 4.2 Thermal Emission of Bodies 62 4.3 The Arrhenius Equation 63 4.4 Saturation Pressure of Water Vapour in Air 64 4.5 Relative Humidity and Mutual Distance Between H20 Molecules 65 4.6 The Liquid State and the Free HzO Molecules in It 65 4.7 The Raoult Law for Ideal Solutions 67 4.8 Ebullition and Freezing 67 4.9 An Additional Aspect of Relative Humidity 68 4.10 The Three Classes of Water Vapour 68 4.11 Conclusions 70 References 70 5. Physics of Drop Formation and Micropore Condensation 5.1 How a Curved Water Meniscus Changes the Equilibrium Vapour Tension 73 5.2 Derivation of the Kelvin Equation for Droplet Formation and Micropore Condensation 75 5.3 The Formation of Droplets in the Atmosphere: Homogeneous and Heterogeneous Nucleation 79 5.4 Bubbles 81 5.5 Micropore Condensation and Stone Weathering 82 5.6 Adsorption Isotherms 87 5.7 Freeze-Thaw Cycles 89 References 91 6. Humidity and Deterioration Mechanisms 6.1 Air-Surface Interactions and Environmental Diagnostics 93 6.2 The Equilibrium Moisture Content and Dimensional Changes in Wood 97 6.3 Mechanisms of Humidity Degradation in Paper and Parchment 101 6.4 Biological Habitat and Vacuum Cleaners 106 6.5 Molecular Layers of Water on the Surface of Metals and Glass 109 6.6 Chemical Forms of Decay 111 6.7 A Complex Structure: The Organ Pipe 112 6.8 What Is the Best Microclimate for Conservation? 114 6.9 Keeping Constant Relative Humidity in Rooms and Showcases 115 6.10 Condensation on Cold Surfaces 119 6.11 People as a Moisture Source 120 References 121 7. Atmospheric Water, Capillary Rise, and Stone Weathering 7.1 Atmospheric Pollution, Acid Rain, Rainfall, and Crusts 125 7 .2 Mechanisms of Penetration of Rainwater and Evaporation 134 7.3 Evaporation From Damp Monuments 135 7.4 Capillary Suction 135 7.5 The Equilibrium Vapour Tension Over a Solution 139 7.6 Climate Cycles, Sea Spray, and Salt Damage 139 7. 7 Deliquescence-Crystallization Cycles 14 2 7.8 Some Common Errors That Should Be Avoided 144 References 150 Further Reading 152 8. Rising Damp Treatment and Prevention 8.1 Measures to Counteract Rising Damp 153 8.2 Removing Causes 154 8.3 Hiding Effects 154 8.4 Damp-Proof Course With Physical Barrier 155 8.5 Damp-Proof Course With Chemical Barrier 155 8.6 Increasing Wall Temperature 157 8.7 Ventilation Within the Wall 158 8.8 Ventilating Outside the Wall 159 8.9 Dehumidifying Plasters 159 8.10 Active Electro-Osmosis 159 8.11 Passive Electro-Osmosis 163 8.12 Parapsychological Devices 163 8.13 Drying Damp Murals 164 References 165 Part II ATMOSPHERIC STABILITY, POLLUTANT DISPERSION AND SOILING OF PAINTINGS AND MONUMENTS 9. Parameters to Describe Air Masses and Vertical Air Motions 9.1 Equivalent Temperature 170 9.2 Adiabatic Gradients in Troposphere 170 9.3 Potential Temperature 171 9.4 Equivalent-Potential Temperature 173 9.5 Virtual Temperature 173 References 174 10. Atmospheric Stability and Pollutant Dispersion 10.1 Introduction 175 10.2 Vertical Temperature Gradients and Plume Behaviour 177 10.3 Effects Due to Topographic Horizontal Inhomogeneity 179 10.4 Urban Climate: Heat Island and Aerodynamic Disturbance 181 10.5 Dispersion and Transportation of Pollutants in a City 182 10.6 Wind Friction Near a Surface 183 10.7 Vertical Fluxes of Heat, Moisture and Momentum 183 10.8 Heat Balance at the Soil or the Monument Surface 185 10.9 Main Parameters Used in Measuring Atmospheric Stability and Turbulence 188 10.10 Plume Dispersion 191 10.11 Stability Classes to Evaluate Atmospheric Stability 191 References 194 11. Dry Deposition of Airborne Particulate Matter-Mechanisms and Effects 11 .1 Introduction 197 11.2 Random Walk and Brownian Diffusivity 199 11.3 Brownian Deposition 201 11.4 Thermophoresis 202 11.5 Diffusiophoresis 204 11.6 Stefan Flow 205 11. 7 Gravitational Settling 207 11.8 Electrophoresis 208 11.9 Photophoresis 210 11.10 Aerodynamic Deposition: Inertial Impaction and Interception 210 11.11 Adhesion of Particles to Paintings or Other Surfaces 215 11.12 Vertical Distribution of Particles in Still Air and Their Resuspension by Turbulence 216 11.13 How Soiling Develops 218 11.14 What ls the Most Appropriate Heating and Air Conditioning System to Avoid Soiling? 221 11.15 Inappropriate Positioning of Paintings 226 11.16 Uplifting of Giant Particles and Wind Erosion 227 11.17 Kinetic Energy and Sand Blasting 232 References 233 Part III RADIATION, LIGHT AND COLOURS 12. Radiometric Aspects of Solar Radiation, Blackbody, and Lamp Radiation 12.1 Radiation Emitted by Bodies and Effects of the Absorbed Energy 237 12.2 Radiometric Temperature 239 12.3 Angular Distribution of Radiant Emission of Bodies 240 12.4 Attenuation of Light in the Atmosphere 241 12.5 Daily and Seasonal Cycles of Solar Radiation on Monuments 241 12.6 Length of Shadow 247 12.7 Electric Lamps for Cultural Heritage 249 12.8 Problems Encountered in Exhibition Lighting 255 12.9 Optical Filters and Optical Fibres 258 12.10 Degradation of Works of Art Caused by Light 264 12.11 Photographic Flash Light 267 12.12 Phototrophic Organisms 268 12.13 Photosensitivity Classes of Materials and Exhibition Lighting Recommended by International Standards 269 References 2 71 13. Photometric Aspects of Visible Light and Colours 13.1 Visible Light and Colour Perception 273 13.2 Trichromatic Theory and Metamers 275 13.3 Munsell Colour System (HSV System) 276 13.4 CIE Chromaticity Diagram 277 13.5 The ROB Additive Light System 279 13.6 The CMY Subtractive Colour System 282 13.7 Transformation Between the ROB and CMY Colour Spaces 285 13.8 The Colour of Objects, Polychromies, and Paintings 286 13.9 Use of Complementary Colours in Visual Arts 288 13.10 Optics of Halftone Imaging and the Neo-Impressionism 290 13.11 How to Improve the Colour Rendering of Electric Lighting 293 13.12 What Is the Colour of Solar Light? 295 References 298 Part IV CLIMATE-RELATED RISKS 14. Climate Change, Human Factor, and Risk Assessment 14.1 Part l: Basic Concepts on Climate Changes, Emission Scenarios and Potential Damage 303 14.2 Part 2: Future Scenarios and Risk Assessment 308 14.3 Part 3: Selected Impact Case Studies 313 References 336 Further Reading 340 Part V EUROPEAN STANDARDS AND FIELD SURVEYS 15. European Standards Concerning Microclimate for Cultural Heritage and Its Measurement 15.1 Introduction. International and European Standards 343 15.2 EN 15757 (2010) and the Priority of Historic Climate 343 15.3 EN 15759-1 (2011) for Heating Churches 347 15.4 EN 15759-2 (2018) for Ventilation in Historic Buildings and to Protect Collections 350 15.5 EN 16883 (2017) for Improving the Energy Performance of Historic Buildings 351 15.6 EN 15758 (2010) for Measuring Temperatures of the Air and Objects 352 15.7 EN 16242 (2012) for Measuring Humidity in the Air and Moisture Exchanges 353 15.8 EN 16682 (2017) for Measurements of Moisture Content in Materials 354 15.9 EN 15999-1 (2013) for Design of Showcases 358 References 358 16. Introduction to Field Measurements 16.1 Field Observations and Computational Fluid Dynamics 359 16.2 Planning Field Measurements 360 16.3 Traditional and Innovative Sensors 362 16.4 Weather Stations and Observations for Monument Conservation 364 16.5 Statistical Representation of Data 367 16.6 Frequency of Observation 368 16.7 Length of Observation Period 369 16.8 Response Time of a Sensor 369 16.9 Drawing Air Temperature and Other Isolines 375 References 378 Part VI MEASURING INSTRUMENTS AND THEIR DEVELOPMENT 17. Measuring Temperature 17.1 Part 1. Historical Overview: The Development of Early Thermometers and Basic Ideas 383 17 .2 Part 2. Modem Technology to Measure Air Temperature 405 17.3 Part 3. Modem Technology to Measure Artwork Surface Temperature 414 References 426 Further Reading 429 18. Measuring Air Humidity 18.1 Part 1. Historical Overview: The Development of Early Hygrometers and Basic Ideas 431 18.2 Part 2. Modem Technology to Measure Air Humidity 441 References 455 19. Measuring Time of Wetness and Moisture in Materials 19.1 Measuring the Time of Wetness 459 19.2 Measuring Moisture in Materials 463 References 479 20. Measuring Wind and Indoor Air Motions 20.1 Part 1: Historical Overview: The Development of Early Anemometers and Basic Ideas 483 20.2 Part 2: Modem Technology to Measure Wind and Air Motions 499 References 509 Further Reading 511 21. Measuring Precipitation and Windborne Drops 21.1 Part 1. Historical Overview: The Development of Early Rain Gauges and Basic Ideas 513 21.2 Part 2. Modern Technology to Measure Precipitation 520 References 532 Appendix 1: List of Fundamental Constants Met in This Book 535 Appendix 2: Summary of Key Equations to Calculate Humidity Variables 537 Appendix 3: Essential Glossary 539 Relevant Objects, Museums, Monuments, etc. Exemplified in Figures 541 Index 547 ER -